A versatile method to produce metallic nickel nanoparticles is demonstrated. Metallic Ni nanoparticles have been synthesized from aqueous solution of NiCl2 using γ-radiation induced reduction. To prevent Ni re-oxidation, post-irradiation treatment was elaborated. Structural and compositional analyses were executed using X-ray diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy. These studies reveal that the synthesized material consists of fcc Ni particles having size of 3.47 ± 0.71 nm. The nanoparticles have a tendency to agglomerate to the larger clusters. The latter are partially oxidized to form thin amorphous/poor-crystalline Ni(OH)2/NiO layers at the surface. Magnetization measurements demonstrate that the nanomaterial exhibit ferromagnetic-like behaviour with magnetization 30% lower than that in bulk Ni. The large active surface area (ECSA, 39.2 m2 g-1) and good electrochemical reversibility, confirmed by the electrochemical studies, make the synthesized material a potential candidate as an active component for energy storage devices.In the present study, solid-state nuclear magnetic resonance (NMR) spectra under magic angle spinning conditions of the rhombohedral structures α-B and B12P2 are reported together with the corresponding parameter sets from first principles calculations on α-B B12X2 (X = P, As, O). With the combination of density functional theory (DFT) and the gauge-including projector-augmented wave (GIPAW) approach as the theoretical tools at hand the computed 11B parameters lead to unambiguous explanation of the measurements. Thereby, we overcome common obstacles of processing recorded NMR spectra of solid-state compounds with several crystallographic positions, in particular non-trivial signal assignments and parameter determination due to peak overlap or even unexpected intensity/area ratios. In fact, we find very good agreement between the theoretical results and measured spectra without applying fitting procedures. Using the Perdew-Burke-Ernzerhof (PBE) functional, the results of the common construction types for pseudopotentials and referencing methods for the chemical shift determination are compared. Suggestions and conclusions from experimental 11B NMR studies on parameters according to the icosahedral positions are critically discussed, for instance the early suspected correlation to chemical shifts is not confirmed. Regarding the electric field gradient (EFG) a detailed explanation for obtaining small deviations amongst all investigated structures of the icosahedral polar sites compared to the equatorial sites is given. Our results show an important link between the exohedral bonding situation of compounds with icosahedral structure elements and the main axis of the EFG and therefore, also measurable quadrupole coupling constants if certain geometrical conditions are fulfilled. Finally, this work also contributes to establishing the number of unique sites measured by solid-state NMR methods within the modification of β-B.In this work, the design and characterization of a multi-cell capacitively coupled contactless conductivity detection system are described. The operation and simultaneous acquisition from 3 detector cells are demonstrated, however, the system is capable of supplying 8 detection cells and can be easily upgraded to maintain 64 capacitively coupled contactless conductivity detection cells. On performing flow-injection analysis, the system recorded as low as 0.01 mM of acetic acid, phosphoric acid, NaH2PO4, and Na2B4O7 solutions in water. The instrument was also capable of recording and distinguishing different mixtures of organic solvents (a) methanol-acetonitrile, (b) hexane-acetone. The designed detection system is expected to be used coupled with multi-channel separation devices for monitoring simultaneous processes. Septoplasty is one of the most frequently performed surgeries. Selleckchem XL413 However, there remains a question as to the effect of such intervention on the sense of smell. This study aims to examine the available evidence regarding the effect of septoplasty on the sense of smell. A database search was performed using PubMed, ScienceDirect, Google Scholar and The Cochrane Library databases from January 1990 to February 2020. Search terms included smell, olfaction, odor, septum, septoplasty, and septorhinoplasty. A meta-analysis was performed with 12 studies that provided sufficient data on change in olfaction. 14 studies met the inclusion criteria, and 2 additional studies were included manually; comprising a total of 996 patients and 25 controls. Significant improvement in olfactory test scores was observed in all tests. Pre- and postoperative differences in means were 0.63 for BSIT, 0.80 for CCCRC test, 1.16 for odor threshold, 1.43 for odor discrimination, and 1.18 for odor identification. Septoplasty seems to improve olfactory function. However, the outcome of this intervention is discrete and not equal for all patients, so further randomized trials are needed to confirm current findings.Septoplasty seems to improve olfactory function. However, the outcome of this intervention is discrete and not equal for all patients, so further randomized trials are needed to confirm current findings. Loss of smell and taste is now recognised as amongst the most common symptoms of COVID-19 and the best predictor of COVID-19 positivity. Long term outcomes are unknown. This study aims to investigate recovery of loss of smell and the prevalence of parosmia. 6-month follow-up of respondents to an online surgery who self-reported loss of smell at the onset of the CO- VID-19 pandemic in the UK. Information of additional symptoms, recovery of loss of smell and the development of parosmia was collected. 44% of respondents reported at least one other ongoing symptom at 6 months, of which fatigue (n=106) was the most prevalent. There was a significant improvement in self-rating of severity of olfactory loss where 177 patients stated they had a normal smell of smell while 12 patients reported complete loss of smell. The prevalence of parosmia is 43.1% with median interval of 2.5 months (range 0-6) from the onset of loss of smell. While many patients recover quickly, some experience long-term deficits with no self-reported improvement at 6 months.

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